[RUCL(P-CYMENE)((S)-DTBM-SEGPHOS)]CL

[RUCL(P-CYMENE)((S)-DTBM-SEGPHOS)]CL - Names and Identifiers

Name	Chloro{(S)-(+)-5,5''-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4''-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride
Synonyms	[RUCL(P-CYMENE)((S)-DTBM-SEGPHOS)]CL (S)-RuCl[(p-cyMene)(DTBM-SEGPHOS)]Cl [RuCl(p-cymene)((S)-dtbm-segphos[R])]Cl [RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos)]Cl Chloro{(S)-(+)-5,5''-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4''-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride Chloro[(S)-(+)-5,5'-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) Chloride Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-dtbm-segphos(R))]Cl
CAS	944451-33-6

[RUCL(P-CYMENE)((S)-DTBM-SEGPHOS)]CL - Physico-chemical Properties

Molecular Formula	C84H112Cl2O8P2Ru
Molar Mass	1483.73
Melting Point	>100°C
Water Solubility	Insoluble in water
Appearance	Powder
Color	orange to brown
Storage Condition	2-8°C
Sensitive	air sensitive

[RUCL(P-CYMENE)((S)-DTBM-SEGPHOS)]CL - Risk and Safety

WGK Germany

[RUCL(P-CYMENE)((S)-DTBM-SEGPHOS)]CL - Introduction

Chloro{(S)-( )-5,5 "-bis[di(3,) phosphino]-4,4"-bi-1,3-benzodioxole (p-cymene)ruthenium(II) chloride is an organometallic compound. The following is a description of its nature, use, formulation and safety information:

Nature:
Chloro{(S)-(-5,5 "-bis[di(3,) phosphino]-4,4"-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride is a solid, usually yellowish crystalline. It is stable at room temperature, but decomposes at high temperatures. It has good solubility in common solvents.

Use:
Chloro{(S)-(5,5 ''-bis[di(3, 3) phosphino]-4,4''-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride are often used in organic synthesis reactions. It is an effective chiral catalyst for asymmetric synthesis, hydrogenation and gas-phase methane carboxylation.

Preparation Method:
Chloro{(S)-(5,5 "-bis[di(3,) phosphino]-4,4"-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride are prepared by a complicated method. A common method of preparation is to first synthesize {(S)-( )-5,5 "-bis [bis (3,5-di-tert-butyl-4-methoxyphenyl) phosphino]-4,4 '-bis-1,3-benzodioxin} and then to obtain the desired compound by reaction with p-toluene and ruthenium chloride.

Safety Information:
For specific safety information chloride Chloro{(S)-(-5,5 ''-phosphino [di(3,)'' bis]-4,4 bi-1,3-benzodioxole}(p-cymene)ruthenium(II), it is recommended to refer to the relevant safety data sheet for this compound. When handling this compound, follow appropriate laboratory safety practices and avoid contact with skin, eyes, and inhalation of its gases. Safety assessments need to be made on a case-by-case basis, including consideration of the potential risks of the compound in terms of toxicity, flammability and explosiveness.

Last Update：2024-04-09 15:18:01